Pyrometallurgical Recovery of Metallic Zinc from Galvanizing Dust by Using Ammonium Chloride Flux

Document Type : یادداشت پژوهشی

Author

Yazd University

Abstract

Having investigated the different reports and various fluxes, ammonium chloride was eventually selected for pyrometallurgical recovery of metallic zinc from the galvanizing flue dust in the present work. This flue dust constitutes 10 to 15 wt.% of galvanizing wastes. The mechanism of ammonium chloride in the extraction of the metallic zinc from the galvanizing dust was explained. Furthermore, the efficiencies of zinc recoveries in the temperature range of 500 to 700 ºC, treating time of 0 to 40 minutes and mixing percentages of 10 to 30wt% fluxes were investigated. The optimum efficiency of zinc recovery was calculated equal to 85% which was observed in the temperature 600ºC, flux mixing ratio of 20wt% and treating time of 20 to 30 minutes.

Keywords


1. Barakat M.A., "The pyrometallurgical processing of galvanizing zinc ash and flue dust", The Journal of The Minerals, Metals & Materials Society, Vol. 55, pp. 26-29, (2003).
2. Bright M.A., Deem N.J., Fryatt J., "The advantages of recycling metallic zinc from the processing wastes of industrial molten zinc applications", The Minerals, Metals & Materials Society, pp. 1-9, (2007).
3. Tolcin A.C., "Zinc" U.S. Geological Survey, Mineral Commodity Summaries, (2015).
4. Dutra A.J.B., Paiva P.R.P., Tavares L.M., "Alkaline leaching of zinc from electric arc furnace steel dust", Minerals Engineering, Vol. 19, pp. 478-485, (2006).
5. Oustadakis P., Tsakiridis P.E., Katsiapi A., Agatzini-Leonardou S., "Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD): Part I: Characterization and leaching by diluted sulphuric acid", Journal of Hazardous Materials, Vol. 179, pp. 1-7, (2010).
6. Rabah M.A., El-Sayed A.S., "Recovery of zinc and some of its valuable salts from secondary resources and wastes", Hydrometallurgy, Vol. 37, pp. 23-32, (1995).
7. Shawabkeh R.A., "Hydrometallurgical extraction of zinc from Jordanian electric arc furnace dust", Hydrometallurgy, Vol. 104, pp. 61-65, (2010).
8. Tsakiridis P.E., Oustadakis P., Katsiapi A., Agatzini-Leonardou S., "Hydrometallurgical process for zinc recovery from electric arc furnace dust (EAFD). Part II: Downstream processing and zinc recovery by electrowinning", Journal of Hazardous Materials, Vol. 179, pp. 8-14, (2010).
9. Serdar Aktas M.A.E.A., "Recovery of zinc from galvanized scraps", Turkish Journal of Engineering and Environmental Sciences, Vol. 26, pp. 395-402, (2002).
10. Matsuoka T., Kurozu S., "Process for recovering valuable metals from an iron dust containing a higher content of zinc", US Patent 5279643 A, (1986).
11. Sakamoto N., Takemoto K., Yamamoto N., Ohkochi I., Iwata Y., "Zinc recovery from zinc-bearing dusts by use of sensible heat of hot metal", ISIJ International, Vol. 35, pp. 1323-1330, (1995).
12. رضوی زاده ح.، "متالورژی سرب و روی"، انتشارات علمی دانشگاه صنعتی شریف, (1392).
13. SÖNmez S., Aktas S., AÇMa E., "A study on the treatment of wastes in hot dip galvanizing plants", Canadian Metallurgical Quarterly, Vol. 42, pp. 289-300, (2003).
14. کریمی زارچی ح. ر.، "استخراج فلز روی از ضایعات غبار صنعتی حاصل از فرایند گالوانیزه"، پنجمین کنفرانس بین المللی مهندسی مواد و متالورژی و دهمین کنفرانس مشترک انجمن مهندسی متالورژی ایران و جامعه ریخته گران ایران, شیراز, (1395).
15. Geerdes M., Toxopeus H., Van Der Vliet C., Chaigneau R., Vander T., "Modern blast furnace ironmaking: an introduction", IOS Press, (2009).
16. Gaskell D.R., "Introduction to the thermodynamics of materials", Taylor & Francis, (2003).
CAPTCHA Image