چکیده انگلیسی Synthesis of graphene-based photocatalyst nanocomposites combined in order to remove the toxic dyes of acid black and acid brown

Document Type : Original Articles

Authors

amir hoshang ramezani ¹

Kareem Khaleel Ibrahim Jburi ²

¹ Department Of Physics ,West Tehran Branch ,Islamic Azad University,Tehran,Iran.

² Department Of Physics,, West Tehran Branch , Islamic Azad University, Tehran, Iran.

10.22067/jmme.2025.91746.1178

Abstract

The synthesize graphene-based photocatalytic nanocomposites incorporating nickel ferrite (NiFe2O4) and nickel oxide (NiO) for the efficient removal of toxic acidic black and acidic brown dyes have been investigated. The synthesis process was meticulously executed using hammer, microwave, and macro-waves methods to enhance the nanocomposite's structure and properties. Comprehensive analytical studies employing scanning electron microscopy (SEM), X-ray diffraction (XRD), vibrating sample magnetometry (VSM), and UV-Vis spectroscopy were conducted to assess the magnetic and photocatalytic characteristics of the synthesized nanocomposites. Additionally, antibacterial tests were performed using Klebsiella bacteria to evaluate the potential antimicrobial properties. The results of the study illustrate the significant impact of the synthesized nanocomposites in removing color pollutants, emphasizing their potential as effective photocatalysts. Furthermore, the nanocomposites exhibit notable antibacterial properties, showcasing their multifunctional applications. The research not only recommends further refinement of the synthesis process and optimization of nanocomposite properties but also suggests broader applications in diverse fields, considering the multifaceted nature of the developed materials.

Keywords

Photocatalytic nanocomposite

Graphene

Nickel ferrite

Nickel oxide

Toxic

Subjects

• Synthesis of Materials

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References

[1] R. Gusain, K. Gupta, P. Joshi, and O. P. Khatri, “Adsorptive removal and photocatalytic degradation of organic pollutants using metal oxides and their composites: A comprehensive review,” Advances in Colloid and Interface Science, vol. 272, p. 102009, 2019. https://doi.org/10.1016/j.cis.2019.102009

[2] K. K. Kefeni and B. B. Mamba, “Photocatalytic application of spinel ferrite nanoparticles and nanocomposites in wastewater treatment,” Sustainable Materials and Technologies, vol. 23, p. e00140, 2020. https://doi.org/10.1016/j.susmat.2019.e00140

[3] W. S. Koe, J. W. Lee, W. C. Chong, Y. L. Pang, and L. C. Sim, “An overview of photocatalytic degradation: photocatalysts, mechanisms, and development of photocatalytic membrane,” Environmental Science and Pollution Research, vol. 27, no. 3, pp. 2522–2565, 2020. https://doi.org/10.1007/s11356-019-07193-5

[4] G. Mamba, G. Gangashe, L. Moss, S. Hariganesh, S. Thakur, S. Vadivel, A. K. Mishra, G. D. Vilakati, V. Muthuraj, and T. T. Nkambule, “State of the art on the photocatalytic applications of graphene based nanostructures: From elimination of hazardous pollutants to disinfection and fuel generation,” Journal of Environmental Chemical Engineering, vol. 8, no. 2, p. 103505, 2020. https://doi.org/10.1016/j.jece.2019.103505

[5] Q. Zhang, L. Jiang, J. Wang, Y. Zhu, Y. Pu, and W. Dai, “Photocatalytic degradation of tetracycline antibiotics using three-dimensional network structure perylene diimide supramolecular organic photocatalyst under visible-light irradiation,” Applied Catalysis B: Environmental, vol. 277, p. 119122, 2020. https://doi.org/10.1016/j.apcatb.2020.119122

[6] G. S. El-Sayyad, M. Abd Elkodous, A. M. El-Khawaga, M. A. Elsayed, A. I. El-Batal, and M. Gobara, “Merits of photocatalytic and antimicrobial applications of gamma-irradiated CoₓNi₁₋ₓFe₂O₄/SiO₂/TiO₂ (x = 0.9) nanocomposite for pyridine removal and pathogenic bacteria/fungi disinfection: Implication for wastewater treatment,” RSC Advances, vol. 10, no. 9, pp. 5241–5259, 2020. https://doi.org/10.1039/C9RA10505K

[7] A. A. Inyinbor, F. A. Adekola, and G. A. Olatunji, “Kinetics, isotherms and thermodynamic modeling of liquid phase adsorption of Rhodamine B dye onto Raphia hookerie fruit epicarp,” Water Resources and Industry, vol. 15, pp. 14–27, 2016. https://doi.org/10.1016/j.wri.2016.06.001

[8] A. A. Oyekanmi, A. Ahmad, K. Hossain, and M. Rafatullah, “Statistical optimization for adsorption of Rhodamine B dye from aqueous solutions,” Journal of Molecular Liquids, vol. 281, pp. 48–58, 2019. https://doi.org/10.1016/j.molliq.2019.02.057

[9] B. L. Pangarkar, M. G. Sane, S. B. Parjane, and M. Guddad, “Status of membrane distillation for water and wastewater treatment—A review,” Desalination and Water Treatment, vol. 52, no. 28–30, pp. 5199–5218, 2014. https://doi.org/10.1080/19443994.2013.808422

[10] A. Pérez-González, A. M. Urtiaga, R. Ibáñez, and I. Ortiz, “State of the art and review on the treatment technologies of water reverse osmosis concentrates,” Water Research, vol. 46, no. 2, pp. 267–283, 2012. https://doi.org/10.1016/j.watres.2011.10.046

[11] M. A. C. K. Hansima, M. Makehelwala, K. B. S. N. Jinadasa, Y. Wei, K. G. N. Nanayakkara, A. C. Herath, and R. Weerasooriya, “Fouling of ion exchange membranes used in the electrodialysis reversal advanced water treatment: A review,” Chemosphere, vol. 263, p. 127951, 2021. https://doi.org/10.1016/j.chemosphere.2020.127951

[12] R. Rosal, A. Rodríguez, J. A. Perdigón-Melón, A. Petre, E. García-Calvo, M. J. Gómez, A. Agüera, and A. R. Fernández-Alba, “Occurrence of emerging pollutants in urban wastewater and their removal through biological treatment followed by ozonation,” Water Research, vol. 44, no. 2, pp. 578–588, 2010. https://doi.org/10.1016/j.watres.2009.07.004

[13] H. Cui, X. Huang, Z. Yu, P. Chen, and X. Cao, “Application progress of enhanced coagulation in water treatment,” RSC Advances, vol. 10, no. 34, pp. 20231–20244, 2020. https://doi.org/10.1039/D0RA02979C

[14] S. Wu, L. Shen, Y. Lin, K. Yin, and C. Yang, “Sulfite-based advanced oxidation and reduction processes for water treatment,” Chemical Engineering Journal, vol. 414, p. 128872, 2021. https://doi.org/10.1016/j.cej.2021.128872

[15] F. Meng, J. Xu, H. Dai, Y. Yu, and D. Lin, “Even incorporation of nitrogen into Fe⁰ nanoparticles as crystalline Fe₄N for efficient and selective trichloroethylene degradation,” Environmental Science & Technology, vol. 56, no. 7, pp. 4489–4497, 2022. https://doi.org/10.1021/acs.est.1c08671

[16] J. Xu, H. Li, and G. V. Lowry, “Sulfidized nanoscale zero-valent iron: Tuning the properties of this complex material for efficient groundwater remediation,” Accounts of Materials Research, vol. 2, no. 6, pp. 420–431, 2021. https://doi.org/10.1021/accountsmr.1c00037

[17] R. Gusain, K. Gupta, P. Joshi, and O. P. Khatri, “Adsorptive removal and photocatalytic degradation of organic pollutants using metal oxides and their composites: A comprehensive review,” Advances in Colloid and Interface Science, vol. 272, p. 102009, 2019. https://doi.org/10.1016/j.cis.2019.102009

[18] Y. Yuan, R. T. Guo, L. F. Hong, X. Y. Ji, Z. S. Li, Z. D. Lin, and W. G. Pan, “Recent advances and perspectives of MoS₂‑based materials for photocatalytic dyes degradation: A review,” Colloids and Surfaces A: Physicochemical and Engineering Aspects, vol. 611, p. 125836, 2021. https://doi.org/10.1016/j.colsurfa.2020.125836

[19] P. A. K. Reddy, P. V. L. Reddy, E. Kwon, K.-H. Kim, T. Akter, and S. Kalagara, “Recent advances in photocatalytic treatment of pollutants in aqueous media,” Environment International, vol. 91, pp. 94–103, 2016. https://doi.org/10.1016/j.envint.2016.02.012

 [20] E. T. Thostenson and T.-W. Chou, “On the elastic properties of carbon nanotube-based composites: Modelling and characterization,” Journal of Physics D: Applied Physics, vol. 36, no. 5, p. 573, 2003. https://doi.org/10.1088/0022-3727/36/5/323

[21] T. Naganuma and Y. Kagawa, “Effect of particle size on the optically transparent nanometer‑order glass particle‑dispersed epoxy matrix composites,” Composites Science and Technology, vol. 62, no. 9, pp. 1187–1189, 2002. https://doi.org/10.1016/S0266-3538(02)00059-3

[22] S. Shaheen, Z. Saeed, A. Ahmad, M. Pervaiz, U. Younas, R. R. M. Khan, R. Luque, and S. Rajendran, “Green synthesis of graphene‑based metal nanocomposite for electro and photocatalytic activity; recent advancement and future prospective,” Chemosphere, vol. 311, p. 136982, 2023. https://doi.org/10.1016/j.chemosphere.2022.136982

[23] R. Giovannetti, E. Rommozzi, M. Zannotti, and C. A. D’Amato, “Recent advances in graphene‑based TiO₂ nanocomposites (GTiO₂Ns) for photocatalytic degradation of synthetic dyes,” Catalysts, vol. 7, no. 10, p. 305, 2017. https://doi.org/10.3390/catal7100305

[24] X. Meng, D. Geng, J. Liu, R. Li, and X. Sun, “Controllable synthesis of graphene‑based titanium dioxide nanocomposites by atomic layer deposition,” Nanotechnology, vol. 22, no. 16, p. 165602, 2011. https://doi.org/10.1088/0957-4484/22/16/165602