Reducing the dimensions of material particles down to nanoscale, can affect the particle properties such as its melting point and equilibrium phase diagram. In this study, a program was developed by MATLAB based on the thermodynamics of surface. The program was used for plotting phase diagrams of nanosystems and comparing it with the bulk ones. According to this study, it was concluded that reducing the particle size to nanoscale leads to lower solidus and liquidus temperatures in the equilibrium phase diagram. Furthermore, reaching to nanoscales decreases the solid solubility regions.
Satyavani T., Kiran B., Kumar et al., "Effect of particle size on DC conductivity, activation energy and diffusion coefficient of lithium iron phosphate in Li-ion cells", Engineering Science and Technology, an International Journal, Vol. 19, No. 1, pp. 40-44, (2016).
Bhatt P., Pratap A., Jha P., "Size and dimension dependent diffusion coefficients of SnO2 nanoparticles", AIP Conference Proceedings, Vol. 1536, No. 1, pp. 237-238, (2013).
Zhang S., "Size-Dependent Diffusion Coefficient in Nanocrystalline Materials", Advanced Materials Research, Vol. 391, pp. 418-421, (2012).
Zeng H., Wu Y., Zhang et al., "Grain size-dependent electrical resistivity of bulk nanocrystalline Gd metals", Progress in Natural Science: Materials International, Vol. 23, No. 1, pp. 18-22, (2013).
Mirjalili M., Vahdati-Khaki J., "Prediction of nanoparticles’ size-dependent melting temperature using mean coordination number concept", Journal of Physics and Chemistry of Solids, Vol. 69, No. 8, pp. 2116-2123, (2008).
Chen C. L., Lee J-G., Arakawa K., Mori H., "Quantitative analysis on size dependence of eutectic temperature of alloy nanoparticles in the Ag–Pb system", Applied Physics Letters, Vol. 98, No. 8, pp. 83-108, (2011).
Garzel G., Janczak-Rusch J., Zabdyr L., "Reassessment of the Ag–Cu phase diagram for nanosystems including particle size and shape effect", Calphad, Vol. 36, pp. 52-56, (2012).
Tanaka T., "Prediction of phase diagrams in nano-sized binary alloys", Materials Science Forum, Vol. 653, pp. 55-75, (2010).
Zhao N., He Y Q., Yang C C., "A new approach to construct bulk and size-dependent continuous binary solution phase diagrams of alloys", RSC Advances, Vol. 5, No. 117, pp. 96323-96327, (2015).
Liang L H., Liu D., Jiang Q., "Size-dependent continuous binary solution phase diagram", Nanotechnology, Vol. 14, No. 4, pp. 438, (2003).
Lu H., Meng X., "Nanophase diagram of binary eutectic Au-Ge nanoalloys for vapor-liquid-solid semiconductor nanowires growth", Scientific reports, Vol. 5, pp. 1-7, (2015).
Tavakoli Khorasani, M. , Teimoory, F. , Mirjalili, M. , & Sahebian, S. (2020). Developing Phase Diagrams for Nano Binary Systems by MATLAB. Journal Of Metallurgical and Materials Engineering, 31(2), 121-130. doi: 10.22067/ma.v31i1.73236
MLA
Masoomeh Tavakoli Khorasani; Farzaneh Teimoory; Mostafa Mirjalili; Samaneh Sahebian. "Developing Phase Diagrams for Nano Binary Systems by MATLAB", Journal Of Metallurgical and Materials Engineering, 31, 2, 2020, 121-130. doi: 10.22067/ma.v31i1.73236
HARVARD
Tavakoli Khorasani, M., Teimoory, F., Mirjalili, M., Sahebian, S. (2020). 'Developing Phase Diagrams for Nano Binary Systems by MATLAB', Journal Of Metallurgical and Materials Engineering, 31(2), pp. 121-130. doi: 10.22067/ma.v31i1.73236
CHICAGO
M. Tavakoli Khorasani , F. Teimoory , M. Mirjalili and S. Sahebian, "Developing Phase Diagrams for Nano Binary Systems by MATLAB," Journal Of Metallurgical and Materials Engineering, 31 2 (2020): 121-130, doi: 10.22067/ma.v31i1.73236
VANCOUVER
Tavakoli Khorasani, M., Teimoory, F., Mirjalili, M., Sahebian, S. Developing Phase Diagrams for Nano Binary Systems by MATLAB. Journal Of Metallurgical and Materials Engineering, 2020; 31(2): 121-130. doi: 10.22067/ma.v31i1.73236
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