سنتز و تعیین مشخصۀ نانوذرات مغناطیسی مس فریت و کاربرد آن‌ها برای حذف رنگ قرمز واکنشی 141 از محیط آبی

نوع مقاله : علمی و پژوهشی

نویسندگان

وحید مجاور ¹

علی احمدپور ²

طاهره روحانی بسطامی ³

وحید محمودی ⁴

¹ گروه مهندسی شیمی دانشکده مهندسی،، دانشگاه فردوسی مشهد، مشهد ، ایران.

² گروه مهندسی شیمی، دانشکده مهندسی، دانشگاه فردوسی مشهد، مشهد، ایران.

³ گروه مهندسی شیمی، دانشکده مهندسی، دانشگاه صنعتی قوچان، قوچان، ایران.

⁴ مجتمع آموزش عالی گناباد

10.22067/jmme.2021.58831.0

چکیده

در این پژوهش، نانوذرات مغناطیسی مس فریت (CuFe₂O₄) با ساختار کریستالی اسپینل فریت (Spinel ferrite) به‌روش حلال گرمایی در محیط اتیلن گلیکول تهیه و برای حذف رنگ قرمز واکنشی (RR141) از محیط آبی به کمک فرایند جذب سطحی به کارگرفته شدند. مطالعه رفتار جذب سطحی RR141 در شرایط مختلف و با تغییر پارامترهای عملیاتی مانند pH محلول، مقدار نانوجاذب، زمان جذب، دمای محلول و غلظت اولیه آلاینده آلی انجام شد. ایزوترم‌های جذب سطحی در محدودۀ ppm 10-50 به‌دست آمدند و نتایج نشان دادند داده‌ها با ایزوترم لانگمویر مطابقت دارند. مطالعۀ سینتیک جذب نشان داد که سینتیک جذب RR141 روی سطح نانوذرات مس فریت از مدل هو تبعیت می‌کند.

کلیدواژه‌ها

نانوذرات مس فریت

خواص مغناطیسی

رنگ قرمز واکنشی 141

فرایند حلال گرمایی

ایزوترم لانگمویر

---

عنوان مقاله English

Synthesis and Characterization of CuFe2O4 Magnetic Nanoparticles and Their Application for Removal of Reactive Red 141 from Aqueous Solution

نویسندگان English

Vahid Mojaver ¹

Ali Ahmadpour ²

Tahereh Rohani Bastami ³

Vahid Mahmoodi ⁴

¹ Student Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad.

² Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad.

³ Department of Chemical Engineering, Faculty of Engineering, Quchan University of Technology.

⁴ Faculty of Engineering, University of Gonabad.

چکیده English

In this research, spinel ferrite (CuFe2O4) magnetic nanoparticles were synthesized by the solvothermal approach in the polyol media and used for the adsorptive removal of Reactive Red 141 (RR 141) as a model of organic dye. Batch adsorption studies were carried out for various pH values, nanoadsorbent loadings, contact times, temperatures, and initial concentrations of the organic pollutant. The adsorption isotherms were in the range of 10–50 ppm and the results fitted well with Langmuir isotherm. The sorption kinetic studies well-defined to Ho’s pseudo-second order model. This research suggests an effective low cost CuFe2O4 nanoadsorbent with a reasonably high efficiency for the removal of RR141 compound, which allows convenient recovery from aqueous media using a weak external magnetic field.

کلیدواژه‌ها English

CuFe2O4 nanoparticles

Magnetic properties

Reactive Red 141 dye

Solvothermal process

Langmuir isotherm

مراجع

1. Rajkumar, D., and Kim, J. G., "Oxidation of various reactive dyes with in situ electro-generated active chlorine for textile dyeing industry wastewater treatment", Journal of hazardous materials, Vol. 136, pp. 203-212, (2006).
2. Yahagi, T., Degawa, M., Seino, Y., Matsushima, T., Nagao, M., Sugimura, T., and Hashimoto, Y., "Mutagenicity of carcinogenic azo dyes and their derivatives", Cancer Letters, Vol. 1, pp. 91-96, (1975).
3. Capalash, N., and Sharma, P., "Biodegradation of textile azo-dyes byPhanerochaete chrysosporium", World journal of microbiology and biotechnology, Vol. 8, pp. 309-312, (1992).
4. Kara, S., Aydiner, C., Demirbas, E., Kobya, M. and Dizge, N., "Modeling the effects of adsorbent dose and particle size on the adsorption of reactive textile dyes by fly ash", Desalination, Vol. 212, pp. 282-293, (2007).
5. Foletto, E. L., Simões, J. M., Mazutti, M. A., Jahn, S. L., Muller, E. I., Pereira, L. S. F., and de Moraes Flores, E. M., "Application of Zn₂SnO₄ photocatalyst prepared by microwave-assisted hydrothermal route in the degradation of organic pollutant under sunlight", Ceramics International, Vol. 39, pp.4569-4574, (2013).
6. Kakarndee, S., and Nanan, S., "SDS capped and PVA capped ZnO nanostructures with high photocatalytic performance toward photodegradation of reactive red (RR141) azo dye", Journal of environmental chemical engineering, Vol. 6, pp. 74-94, (2018).
7. Juabrum, S., Chankhanittha, T., and Nanan, S, "Hydrothermally grown SDS-capped ZnO photocatalyst for degradation of RR141 azo dye", Materials Letters, Vol. 245, pp. 1-5, (2019).
8. Almeida, E., and Corso, C., "Decolorization and removal of toxicity of textile azo dyes using fungal biomass pelletized", International Journal of Environmental Science and Technology, Vol. 16, pp. 1319-1328, (2019).
9. Xu, X. R., and Li, X. Z., "Degradation of azo dye Orange G in aqueous solutions by persulfate with ferrous ion", Separation and purification technology, Vol. 72, pp. 105-111, (2010).
10. Mendes, C., Dilarri, G., Bidoia, E., Montagnolli, R., and Corso, C., "Biodegradation study of azo dye Direct Orange 39 by Saccharomyces cerevisiae in a vertical bioreactor", Exploring Microorganisms: Recent Advances in Applied Microbiology, Brown alker press, Vol. 1, pp. 45-49, (2018).
11. Jin, X., Li, S., Long, N., and Zhang, R., "Improved biodegradation of synthetic Azo dye by anionic cross-linking of chloroperoxidase on ZnO/SiO₂ nanocomposite support", Applied biochemistry and biotechnology, Vol. 184, pp. 1009-1023, (2018).
12. Ajaz, M., Elahi, A., and Rehman, A. "Degradation of azo dye by bacterium, Alishewanella sp. CBL-2 isolated from industrial effluent and its potential use in decontamination of wastewater", Journal of Water Reuse and Desalination, Vol. 8, pp. 507-515, (2018).
13. Bouras, H. D., Isik, Z., Arikan, E. B., Bouras, N., Chergui, A., Yatmaz, H. C., and Dizge, N., "Photocatalytic oxidation of azo dye solutions by impregnation of ZnO on fungi", Biochemical Engineering Journal, Vol. 146, pp. 150-159, (2019).
14. Najafian, H., Manteghi, F., Beshkar, F., and Salavati-Niasari, M., "Enhanced photocatalytic activity of a novel NiO/Bi₂O₃/Bi₃ClO₄ nanocomposite for the degradation of azo dye pollutants under visible light irradiation", Separation and Purification Technology, Vol. 209, pp. 6-17, (2019).
15. Kafil, M., Nasab, S. B., Moazed, H., Jokiniemi, J., Lahde, A., and Bhatnagar, A., "Efficient removal of azo dyes from water with chitosan/carbon nanoflower as a novel nanocomposite synthesized by pyrolysis technique", Desalination and Water Treatment, Vol. 142, pp. 308-320, (2019).
16. Ahmad, A., and Hameed, B., "Fixed-bed adsorption of reactive azo dye onto granular activated carbon prepared from waste", Journal of hazardous materials, Vol. 175, pp. 298-303, (2010).
17. Netpradit, S., Thiravetyan, P., and Towprayoon, S., "Application of ‘waste’metal hydroxide sludge for adsorption of azo reactive dyes", Water Research, Vol. 37, pp. 763-772, (2003).
18. Gupta, V., Mittal, A., Gajbe, V., and Mittal, J., "Removal and recovery of the hazardous azo dye acid orange 7 through adsorption over waste materials: bottom ash and de-oiled soya", Industrial & engineering chemistry research, Vol. 45, pp. 1446-1453, (2006).
19. Gupta, V., Gupta, B., Rastogi, A., Agarwal, S., and Nayak, A., "A comparative investigation on adsorption performances of mesoporous activated carbon prepared from waste rubber tire and activated carbon for a hazardous azo dye-Acid Blue 113", Journal of Hazardous Materials, Vol. 186, pp. 891-901, (2011).
20. Zehra, T., Priyantha, N., Lim, L. B., and Iqbal, E., "Sorption characteristics of peat of Brunei Darussalam V: removal of Congo red dye from aqueous solution by peat", Desalination and Water Treatment, Vol. 54, pp. 2592-2600, (2015).
21. Shokoohi, R., Vatanpoor, V., Zarrabi, M., and Vatani, A., "Adsorption of Acid Red 18 (AR18) by activated carbon from poplar wood-A kinetic and equilibrium study", Journal of Chemistry, Vol. 7, pp. 65-72, (2010).
22. Dave, P. N., Kaur, S., and Khosla, E. "Removal of Eriochrome black-T by adsorption on to eucalyptus bark using green technology", Indian Journal of Chemical Technology, Vol. 18, pp. 53-60, (2011).
23. Abdullah, A. L., Salleh, M. M., Mazlina, M. S., Noor, M., Osman, M., Wagiran, R., and Sobri, S., "Azo dye removal by adsorption using waste biomass: sugarcane bagasse", International Journal of engineering and technology, Vol. 2, pp. 8-13, (2005).
24. Cheung, W., Szeto, Y., and McKay, G., "Intraparticle diffusion processes during acid dye adsorption onto chitosan", Bioresource technology, Vol. 98, pp. 2897-2904, (2007).
25. Nong, L., Xiao, C., and Jiang, W., "Azo dye removal from aqueous solution by organic-inorganic hybrid dodecanoic acid modified layered Mg-Al hydrotalcite", Korean Journal of Chemical Engineering, Vol. 28, pp. 933-938, (2011).
26. Cao, C., Xiao, L., Chen, C., Shi, X., Cao, Q., and Gao, L., "In situ preparation of magnetic Fe₃O₄/chitosan nanoparticles via a novel reduction–precipitation method and their application in adsorption of reactive azo dye", Powder technology, Vol. 260, pp. 90-97, (2014).
27. Zhu, H.Y., Jiang, R., Xiao, L., and Li, W., "A novel magnetically separable γ-Fe₂O₃/crosslinked chitosan adsorbent: preparation, characterization and adsorption application for removal of hazardous azo dye", Journal of Hazardous Materials, Vol. 179, pp. 251-257, (2010).
28. Zhang, Z., and Kong, J., "Novel magnetic Fe₃O₄@C nanoparticles as adsorbents for removal of organic dyes from aqueous solution", Journal of hazardous materials, Vol. 193, pp. 325-329, (2011).
29. Yu, F., Chen, J., Chen, L., Huai, J., Gong, W., Yuan, Z., Ma, J., "Magnetic carbon nanotubes synthesis by Fenton’s reagent method and their potential application for removal of azo dye from aqueous solution", Journal of colloid and interface science, Vol. 378, pp. 175-183, (2012).
30. Agouriane, E., Rabi, B., Essoumhi, A., Razouk, A., Sahlaoui, M., Costa, B., and Sajieddine, M., "Structural and magnetic properties of CuFe₂O₄ ferrite nanoparticles synthesized by co-precipitation", Journal of Materials and Environmental Science, Vol. 7, pp. 4116-4120, (2016).
31. Jiang, J., Goya, G., and Rechenberg, H. R., "Magnetic properties of nanostructured CuFe₂O₄", Journal of Physics: Condensed Matter, Vol. 11, pp. 4063, (1999).
32. Yaman, C., and Gündüz, G., "A parametric study on the decolorization and mineralization of CI Reactive Red 141 in water by heterogeneous Fenton-like oxidation over FeZSM-5 zeolite", Journal of Environmental Health Science & Engineering, Vol. 13, pp. 1-12, (2015).
33. Abolhasani, S., Ahmadpour, A., Bastami, T. R., and Yaqubzadeh, A., "Facile synthesis of mesoporous carbon aerogel for the removal of ibuprofen from aqueous solution by central composite experimental design (CCD)", Journal of Molecular Liquids, Vol. 281, pp. 261-268, (2019).
34. Zhu, Z., Li, X., Zhao, Q., Li, Y., Sun, C., and Cao, Y., "Photocatalytic performances and activities of Ag-doped CuFe₂O₄ nanoparticles", Materials Research Bulletin, Vol. 48, pp. 2927-2932, (2013).
35. Selvan, R. K., Augustin, C., Berchmans, L. J., and Saraswathi, R., "Combustion synthesis of CuFe₂O₄", Materials Research Bulletin, Vol. 38, pp. 41-54, (2003).
36. Zhao, J., Cheng, Y., Yan, X., Sun, D., Zhu, F., and Xue, Q., "Magnetic and electrochemical properties of CuFe₂O₄ hollow fibers fabricated by simple electrospinning and direct annealing", CrystEngComm, Vol. 14, pp. 5879-5885, (2012).
37. Vergis, B. R., Krishna, R. H., Kottam, N., Nagabhushana, B., Sharath, R., and Darukaprasad, B., "Removal of malachite green from aqueous solution by magnetic CuFe₂O₄ nano-adsorbent synthesized by one pot solution combustion method", Journal of Nanostructure in Chemistry, Vol. 8, pp. 1-12, (2018).
38. Krishna, R. H., and Swamy, A., "Physico-Chemical Key Parameters, Langmuir and Freundlich isotherm and Lagergren Rate Constant Studies on the removal of divalent nickel from the aqueous solutions onto powder of calcined brick", International Journal of Engineering Research and Development, Vol. 4, pp. 29-38, (2012).
39. Bastami, T. R., and Entezari, M. H., "Activated carbon from carrot dross combined with magnetite nanoparticles for the efficient removal of p-nitrophenol from aqueous solution", Chemical engineering journal, Vol. 210, pp. 510-519, (2012).