سنتز و تعیین مشخصۀ نانوذرات مغناطیسی مس فریت و کاربرد آن‌ها برای حذف رنگ قرمز واکنشی 141 از محیط آبی

نوع مقاله : علمی و پژوهشی

نویسندگان

1 گروه مهندسی شیمی دانشکده مهندسی،، دانشگاه فردوسی مشهد، مشهد ، ایران.

2 گروه مهندسی شیمی، دانشکده مهندسی، دانشگاه فردوسی مشهد، مشهد، ایران.

3 گروه مهندسی شیمی، دانشکده مهندسی، دانشگاه صنعتی قوچان، قوچان، ایران.

4 مجتمع آموزش عالی گناباد

چکیده

در این پژوهش، نانوذرات مغناطیسی مس فریت (CuFe2O4) با ساختار کریستالی اسپینل فریت (Spinel ferrite) بهروش حلال گرمایی در محیط اتیلن گلیکول تهیه و برای حذف رنگ قرمز واکنشی (RR141) از محیط آبی به کمک فرایند جذب سطحی به کارگرفته شدند. مطالعه رفتار جذب سطحی RR141 در شرایط مختلف و با تغییر پارامترهای عملیاتی مانند pH محلول، مقدار نانوجاذب، زمان جذب، دمای محلول و غلظت اولیه آلاینده آلی انجام شد. ایزوترمهای جذب سطحی در محدودۀ ppm 10-50 بهدست آمدند و نتایج نشان دادند دادهها با ایزوترم لانگمویر مطابقت دارند. مطالعۀ سینتیک جذب نشان داد که سینتیک جذب RR141 روی سطح نانوذرات مس فریت از مدل هو تبعیت میکند.

کلیدواژه‌ها


عنوان مقاله [English]

Synthesis and Characterization of CuFe2O4 Magnetic Nanoparticles and Their Application for Removal of Reactive Red 141 from Aqueous Solution

نویسندگان [English]

  • Vahid Mojaver 1
  • Ali Ahmadpour 2
  • Tahereh Rohani Bastami 3
  • Vahid Mahmoodi 4
1 Student Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad.
2 Department of Chemical Engineering, Faculty of Engineering, Ferdowsi University of Mashhad.
3 Department of Chemical Engineering, Faculty of Engineering, Quchan University of Technology.
4 Faculty of Engineering, University of Gonabad.
چکیده [English]

In this research, spinel ferrite (CuFe2O4) magnetic nanoparticles were synthesized by the solvothermal approach in the polyol media and used for the adsorptive removal of Reactive Red 141 (RR 141) as a model of organic dye. Batch adsorption studies were carried out for various pH values, nanoadsorbent loadings, contact times, temperatures, and initial concentrations of the organic pollutant. The adsorption isotherms were in the range of 10–50 ppm and the results fitted well with Langmuir isotherm. The sorption kinetic studies well-defined to Ho’s pseudo-second order model. This research suggests an effective low cost CuFe2O4 nanoadsorbent with a reasonably high efficiency for the removal of RR141 compound, which allows convenient recovery from aqueous media using a weak external magnetic field.

کلیدواژه‌ها [English]

  • CuFe2O4 nanoparticles
  • Magnetic properties
  • Reactive Red 141 dye
  • Solvothermal process
  • Langmuir isotherm
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