مهندسی متالورژی و مواد

مهندسی متالورژی و مواد

بررسی تاثیر پیش‌فرآوری گل قرمز به روش آب شویی بر فعالیت آن در تولید سوخت بیودیزل

نوع مقاله : علمی و پژوهشی

نویسندگان
آرش بدری
حامد نایب زاده
بهگام رحمانی وحید
گروه مهندسی شیمی، دانشکده مهندسی شیمی و مواد، دانشگاه صنعتی اسفراین، اسفراین، خراسان شمالی.
10.22067/jmme.2026.93435.1208
چکیده
در این پژوهش، گل قرمز تهیه شده از شرکت آلومینا ایران به منظور تبدیل به یک کاتالیست مناسب برای تولید سوخت سبز بیودیزل به روش آب‌شویی پیش فرآوری شد. گل قرمز توسط آنالیزهای XRF، XRD، FTIR، BET و FESEM تعیین مشخصات شد و فعالیت آن به عنوان کاتالیست در فرایند تبدیل اولئیک اسید به بیودیزل مورد ارزیابی قرار گرفت. نتایج نشان داد که پیش فرآوری خصوصیات فیزیکی و شیمیایی را بطور چشمگیری بهبود می بخشد بطوری‌که باحذف یون-های زائد سطحی مانند سدیم، اکسیدهای فلزی مانند آهن، سیلیس و آلومینیوم سهم بیشتری از کاتالیست را به خود اختصاص داده و بتوانند فعالیت کاتالیست را بهبود بخشند. همچنین مساحت سطح نمونه تقریبا دو برابر شده است که می تواند تاثیر مستقیمی بر فعالیت کاتالیست گل قرمز پیش فرآوری شده داشته باشد. به علاوه میانگین اندازه حفرات نیز کاهش یافته است که نشاندهنده باز شدن خلل و فرج کوچک بوده است که توسط یون های زائد پرشده بوده است که همگی تاثیر مستقیم بر فعالیت کاتالیست دارند به نحوی که بررسی فعالیت نمونه در واکنش استری نشان داد که با پیش فرآوری گل قرمز میزان تبدیل اولئیک اسید به بیودیزل از 7/62% به 6/74% افزایش یافت. بنابر نتایج پژوهش گل قرمز می تواند یک گزینه مناسب و جذاب برای کاربرد به عنوان کاتالیست در فرایندهای شیمیایی بعد از بهبود خصوصیات آن باشد.
کلیدواژه‌ها
گل قرمز
پیش فرآوری گل قرمز
کاتالیست ناهمگن
بیودیزل
واکنش استری
موضوعات

عنوان مقاله English

Investigating the effect of red mud pretreatment by water on its activity in biodiesel production

نویسندگان English

Arash Badri
Hamed Nayebzadeh
Behgam rahmanivahid
Department of Chemical Engineering, Esfarayen University of Technology, Esfarayen, Iran.
چکیده English

In this study, red mud obtained from Alumina Iran Company was pretreated by water leaching to become a suitable catalyst for the production of green biodiesel fuel. The red mud was characterized by XRF, XRD, FTIR, BET and FESEM analyses and its activity as a catalyst in the process of converting oleic acid to biodiesel was evaluated. The results showed that pretreatment significantly improves the physical and chemical properties, such that by removing surface ions such as sodium, metal oxides such as iron, silica and aluminum occupy a larger share of the catalyst and can improve the catalyst activity. Also, the surface area of ​​the sample has almost doubled, which can have a direct impact on the catalyst activity of the pretreated red mud. In addition, the average pore size also decreased, indicating the opening of small pores filled with excess ions, all of which have a direct effect on the activity of the catalyst. In a way, the study of the activity of the sample in the esterification reaction showed that with the pretreatment of red mud, the conversion rate of oleic acid to biodiesel increased from 62.7% to 74.6%. According to the results of the study, red mud can be a suitable and attractive option for use as a catalyst in chemical processes after improving its properties.

کلیدواژه‌ها English

Red mud
Red mud pretreatment
Heterogeneous catalyst
Biodiesel
Esterification reaction
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